Effect of in-situ formation of columnar mullite and pore structure refinement on high temperature properties of corundum casatbles

The effects of in-situ synthesis columnar mullite and pore structure on the hot modulus of rupture (HMOR), thermal shock resistance and corrosion resistance of corundum castables have been investigated in this paper. When 2% nano silica was added, the pore diameters of castables could be decreased to 15 nm (at 110 °C), 1 μm (1100 °C) and 6 μm (1500 °C), respectively. The corresponding reducing magnitude of pore size is 98.5%, 83.3% and 33.3%. The HMOR of castables fired at 1500 °C increased by 110% to 3.64 MPa. Furthermore, after three thermal shock cycles, the residual strength ratio of castables increased from 5.2% to 15.3%. A large amount of cross-distributed columnar mullite was formed between nano silica and α-Al₂O₃ by the two-dimensional nucleation mechanism, which remarkably enhanced the high temperature properties. The penetration index reduced from 30.86% to 19.88%, suggesting that smaller pore size and higher viscosity had a great influence to the penetration process.     

退火温度对冷轧DP980钢力学性能的影响

利用连续退火模拟机对DP980试验钢进行了连续退火试验,并通过扫描电镜、电子背散射衍射、透射电镜等研究了不同退火温度下(775、800、825和850 ℃),试验钢显微组织的演变规律和力学性能的变化趋势。结果表明:试验钢的屈服强度随着退火温度的升高而不断增大(从705 MPa增大到850 MPa),抗拉强度和断后伸长率则随着退火温度的升高而不断减小(抗拉强度从1150 MPa减小到1030 MPa;伸长率从8.9%减小到5.3%),这与试验钢的显微组织构成和形态分布密切相关。此外,不同退火温度下,试验钢的加工硬化率曲线均呈现单调下降的趋势。     

化学气相沉积钨涂层的研究现状与进展

化学气相沉积钨涂层具有工艺简单、技术成熟度高、涂层综合质量优异等特点，广泛应用于国防、航天、核工业等领域。首先介绍了化学气相沉积钨涂层的原理和特点，重点讨论了化学气相沉积钨涂层的工艺及应用研究现状，包括化学气相沉积钨涂层微观组织控制工艺及在耐辐射、耐磨耐蚀和高温防护领域的应用，同时对新型化学气相沉积钨涂层技术的发展进行了展望。一是改善现有工艺存在的反应气源与反应产物毒性大等问题，满足绿色环保的发展要求；二是改善现有工艺存在的沉积温度高、沉积速率偏低等问题，实现在不同衬底表面的高效、高质量沉积；三是改善现有化学气相沉积钨涂层结构与功能单一等问题，满足构件对钨涂层高性能和多功能的需求。     

DP980+Z烘烤硬化值与退火温度的关系

摘要：为了研究退火温度对镀锌DP980+Z烘烤硬化值的影响，退火温度控制在760～820℃之间，系统分析退火温度对烘烤硬化值的影响。通过准静态拉伸试验机测量烘烤硬化值及抗拉强度，采用lepara试剂对组织中的马氏体进行着色，利用金相显微镜及图像处理软件测量马氏体的体积分数；采用扫描电镜观察DP980+Z的双相组织特点，并且将组织图片通过CAD转化成有限元图进行网格划分，建立代表性体积单元（RVE），通过有限元分析铁素体、马氏体强度对烘烤硬化值的影响。在同样的变形量情况下，DP980+Z的原始屈服强度越高，烘烤硬化值越高。     

温度对生物净化滤柱中氨氮、铁、锰去除效果的影响

温度是生物净化滤柱运行的一个重要参数，采用生物净化滤柱处理模拟含氨氮、铁、锰地下水，考察水温从约25℃降到约6℃过程中氨氮、铁、锰的去除效果。结果表明，出水氨氮、总铁、锰的浓度分别低于0.15mg/L、0.1mg/L、0.05mg/L，均低于国家标准。出水总铁、锰均未受到水温下降的影响，但是出水氨氮浓度逐渐从约0.02mg/L升高到约0.12mg/L。进一步分析发现，铁主要在滤层的0~0.4m段去除，去除效果没有受到水温变化的影响。氨氮、锰主要在滤层的0~0.8m段去除，其沿程浓度均随水温降低而明显升高。氨氮、锰的生物去除符合一级动力学反应，水温为24.6℃、15.3℃、6.7℃时，两者的动力学常数k分别为0.154min^-1、0.186min^-1，0.143min^-1、0.175min^-1，0.103min^-1、0.163min^-1；半反应时间t_1/2分别为4.51min、3.72min，4.83min、3.96min，6.72min、4.24min。随着试验水温的降低，氨氮、锰的去除效果明显受到影响。     

Highly stretchable self-sensing actuator based on conductive photothermally-responsive hydrogel

Soft robots built with active soft materials have been increasingly attractive. Despite tremendous efforts in soft sensors and actuators, it remains extremely challenging to construct intelligent soft materials that simultaneously actuate and sense their own motions, resembling living organisms’ neuromuscular behaviors. This work presents a soft robotic strategy that couples actuation and strain-sensing into a single homogeneous material, composed of an interpenetrating double-network of a nanostructured thermo-responsive hydrogel poly(N-isopropylacrylamide) (PNIPAAm) and a light-absorbing, electrically conductive polymer polypyrrole (PPy). This design grants the material both photo/thermal-responsiveness and piezoresistive-responsiveness, enabling remotely-triggered actuation and local strain-sensing. This self-sensing actuating soft material demonstrated ultra-high stretchability (210%) and large volume shrinkage (70%) rapidly upon irradiation or heating (13%/°C, 6-time faster than conventional PNIPAAm). The significant deswelling of the hydrogel network induces densification of percolation in the PPy network, leading to a drastic conductivity change upon locomotion with a gauge factor of 1.0. The material demonstrated a variety of precise and remotely-driven photo-responsive locomotion such as signal-tracking, bending, weightlifting, object grasping and transporting, while simultaneously monitoring these motions itself via real-time resistance change. The multifunctional sensory actuatable materials may lead to the next-generation soft robots of higher levels of autonomy and complexity with self-diagnostic feedback control.     

淬火温度对G105钢组织和性能的影响

利用硬度计、拉伸试验机、冲击试验机和光学显微镜等手段,研究了G105钢分别在890、910和930 ℃保温150 min淬火,随后进行630 ℃保温180 min回火处理后组织和性能变化。结果表明:随着淬火温度的升高,G105钢淬火硬度越来越高;经回火处理后,淬火温度为890 ℃和910 ℃时,调质硬度无太大差异,分别为33.2 HRC和32.7 HRC,淬火温度为930 ℃的调质硬度相对提高约1.5 HRC。试验钢强度随着淬火温度的升高也呈现升高趋势,但冲击韧性呈先升高后下降的趋势,这主要是由于调质后存在粒状碳化物的析出现象,导致其冲击韧性显著下降,故认为当淬火温度选取910 ℃时,获得的G105钢综合力学性能较佳。     

55SiCr弹簧钢中的残留奥氏体与碳化物

通过扫描电镜(SEM)、电子背散射衍射(EBSD)、透射电镜(TEM)、X射线衍射仪(XRD)、热膨胀仪、洛氏硬度计等手段研究了弹簧钢55SiCr的组织和相变点以及残留奥氏体和碳化物在热处理过程中的组织演变。结果表明:55SiCr弹簧钢淬火后残留奥氏体以块状分布在基体上;随回火温度的升高,残留奥氏体减少并呈粒状和薄膜状分布;C在残留奥氏体中富集,使其稳定性增强;Si抑制了碳化物的析出,提高了残留奥氏体的稳定性。低温回火时,Si延缓了渗碳体析出;高温回火时,C原子扩散速率提高,促进渗碳体析出,引起体积的收缩。慢速加热回火时,C有足够的时间扩散,从而促进渗碳体的形成,使渗碳体的形成温度提前;快速加热回火时,C来不及扩散,抑制了渗碳体的析出。回火加热速率一样时,试验钢的硬度随回火温度的提高而下降。当回火温度为400 ℃时,硬度值最大为51 HRC;当回火温度为650 ℃时,硬度值最小为37 HRC。当加热速率为0.1 ℃/s时,硬度值最小为33 HRC;当加热速率为200 ℃/s时,硬度值最大为40 HRC。     

A Constitutive Equation of Thermoelasticity for Solid Materials

A new constitutive equation of thermoelasticity for crystals is presented based on the interatomic potential and solid mechanics at finite temperature. Using the new constitutive equation, the calculations for crystal copper and graphene are carried out under different loading paths at different temperatures. The calculated results are in good agreement with those of the previous thermoelasticity constitutive equation based on quantum mechanics, which clearly indicates that our new constitutive equation of thermoelasticity is correct. A lot of comparisons also show that the present theory is more concise and efficient than the previous thermal stress theory in the practical application.     

热处理工艺对30MnCrNiMo高强钢组织与性能的影响

借助全自动淬火膨胀仪测定钢的Ac₁、Ac₃相变点,通过对试验钢进行淬火+亚温淬火+回火热处理和淬火+回火热处理,研究了两种热处理工艺下30MnCrNiMo高强钢的组织与性能。结果表明:30MnCrNiMo高强钢的Ac₁、Ac₃相变点分别为653、807 ℃。采用淬火+亚温淬火+回火的热处理工艺所获得的马氏体和铁素体复相组织比直接淬火+回火得到的全马氏体组织更为细小、均匀,试验钢的屈服强度为1499 MPa,伸长率为14.0%,室温、-40 ℃冲击吸收能量分别为35.5和29.5 J,钢的塑性和冲击性能显著提升,有效改善了30MnCrNiMo高强钢的强韧性能。